An Unusual Mixed-Valence Cu(I)−Cu(II) 3-D Framework
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https://figshare.com/articles/dataset/An_Unusual_Mixed_Valence_Cu_I_Cu_II_3_D_Framework/3345589
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资源简介：
The reaction of Cu(CH3CN)4ClO4 with 2-pyridylacrylic acid (2-HPYA)
affords an unusual mixed-valence Cu(I)−Cu(II) 3-D framework
{[Cu(II)(2-PYA)2]3·[Cu(I)(2-PYA)]2·(H2O)2}n (1) with a novel topology
which features Cu(II) dimeric units (or paddle-wheel unit). The
almost perpendicular coordinating direction between the N atom
of pyridyl and the O atom of carboxylate groups may be responsible
for the formation of such a novel network.
创建时间：
2016-05-07
