Intramolecular Methylation of an Allyl Sulfone via Lithium Alkoxyaluminate; Application to the Enantioselective Synthesis of the CD Ring of Vitamin D<sub>3</sub>
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资源简介：
Alcohol-directed intramolecular methylation of an enantiopure allyl sulfone using AlMe3 provides a trans-hydrindane CD ring alcohol. The substrate cis-CD ring allyl sulfone alcohol is prepared via intramolecular allyl sulfonyl anion addition to aldehyde using Ba(OH)2.
创建时间：
2016-02-20
