Selenoxopropadienylidene (CCCSe) as a Bridging Ligand
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Selenoxopropadienylidene_CCCSe_as_a_Bridging_Ligand/2217988
下载链接
链接失效反馈官方服务：
资源简介：
The
reaction of [W(CCCSiMe3)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with
[nBu4N]F and selenium in the
presence of [RuCl(PPh3)2(η-C5H5)] affords a mixture of the tricarbido complex [WRu(μ-CCC)(CO)2(PPh3)2(η-C5H5)(Tp*)] and the selenoxopropadienylidene (C3Se)
complex [WRu(μ-CCCSe)(CO)2(PPh3)2(η-C5H5)(Tp*)], both of
which were structurally characterized. The formation of the bimetallic
C3Se complex is consistent with the intermediacy of the
salt [nBu4N] [W(CCCSe)(CO)2(Tp*)], which could be observed spectroscopically and computationally
interrogated, but not yet isolated.
创建时间：
2015-01-12
