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Pyridine Ring Opening at Room Temperature at a Rhenium Tricarbonyl Bipyridine Complex

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Pyridine_Ring_Opening_at_Room_Temperature_at_a_Rhenium_Tricarbonyl_Bipyridine_Complex/2942320 数据链接链接失效反馈

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Pyridine Ring Opening at Room Temperature at a Rhenium Tricarbonyl Bipyridine Complex

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创建时间：

2016-02-27

有机金属催化

杂环化合物构建

Reactions of tantallacarborane methyl complexes ([η1:η5-(Me2NCH2CH2)C2B9H10]TaMe3 (1) and [η1:η5-(MeOCH2CH2)C2B9H10]TaMe3 (8)) with alkyl isonitriles have been studied. Complex 1 reacted with 1 eq

Figshare2016-02-12 更新70

Osmium Models of Intermediates Involved in Catalytic Reactions of Alkylidenecyclopropanes

有机金属催化

反应中间体

The complex [OsCp{κ3-P,C,C-PiPr2[C(CH3)CH2]}(CH3CN)]PF6 (1) reacts with (2-pyridyl)methylenecyclopropane, at room temperature, to give initially the cyclobutylidene derivative [Os(η5-C5H5)(CC

NIAID Data Ecosystem60

Activation of Epoxides by a Cooperative Iron–Thiolate Catalyst: Intermediacy of Ferrous Alkoxides in Catalytic Hydroboration

有机金属催化

环氧化物

This paper describes a cooperative iron–thiolate catalyst Cp*Fe(1,2-Ph2PC6H4S)(NCMe) (Cp*– = C5Me5–, [1(NCMe)]) for regioselective hydroboration of aryl epoxide by pinacolborane (HBpin). The critica

Figshare2017-10-13 更新20

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

有机金属催化

反应机理

New experimental findings suggest partial revision of the currently accepted mechanism of the carbonyl hydrosilylation catalyzed by the iridium(III) pincer complex introduced by Brookhart. Employing

NIAID Data Ecosystem60

Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex

有机金属催化

硼烷化合物合成

Selective B–O–Si bond formation was achieved in the reaction of bisboryloxide O(Bpin)2 (pin = (OCMe2)2)/boroxine (MeBO)3 system with tertiary silane R3SiH in the presence of stoichiometric water and

NIAID Data Ecosystem60

Pyridine Ring Opening at Room Temperature at a Rhenium Tricarbonyl Bipyridine Complex

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