New Systematic Route to Mixed-Valence Triiron Clusters Derived from Dinuclear Models of the Active Site of [Fe–Fe]-Hydrogenases
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https://figshare.com/articles/dataset/New_Systematic_Route_to_Mixed_Valence_Triiron_Clusters_Derived_from_Dinuclear_Models_of_the_Active_Site_of_Fe_Fe_Hydrogenases/2232694
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资源简介：
A novel
reaction pathway to synthesize the linear trinuclear clusters
[Fe3(CO)5(κ2-diphosphine)(μ-dithiolate)2] via the direct reaction of the dinuclear hexacarbonyl precursor
[Fe2(CO)6(μ-dithiolate)] with the mononuclear
species [Fe(CO)2(κ2-diphosphine)(κ2-dithiolate)] has been developed with diphosphine (dppe) and
dithiolate (pdt = propanedithiolate) (1) or adtBn ({SCH2}2NBn = azadithiolate) (2). A crystallographic study was carried out on 2 and
Mössbauer spectroscopy, and DFT calculations have been used
to describe the electronic and structural properties of 1. The electrochemical properties of 1 in the absence
and in the presence of a weak acid have been the subject of a preliminary
investigation.
创建时间：
2016-02-16
