Construction of Benzo-1,2,3-thiazaphosphole Heterocycles by Annulations of ortho-Phosphinoarenesulfonyl Fluorides with Trimethylsilyl Azide
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https://figshare.com/articles/dataset/Construction_of_Benzo-1_2_3-thiazaphosphole_Heterocycles_by_Annulations_of_i_ortho_i_-Phosphinoarenesulfonyl_Fluorides_with_Trimethylsilyl_Azide/12918912
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资源简介：
Annulations of ortho-phosphinoarenesulfonyl fluorides with trimethylsilyl azide were developed to access an unprecedented benzo-1,2,3-thiazaphosphole heterocycle. A corresponding reaction mechanism was proposed and further elucidated by experimental and computational studies. The reaction proceeds through a Staudinger-type iminophosphorane intermediate followed by intramolecular trapping with sulfonyl fluoride.
创建时间：
2020-09-04
