A Pentahydrated Diorganotin Cation. Cocrystallization of [{<i>n</i>-Bu<sub>2</sub>Sn(H<sub>2</sub>O)<sub>5</sub>}][CF<sub>3</sub>SO<sub>3</sub>]<sub>2</sub> and [{<i>n</i>-Bu<sub>2</sub>Sn(BPDO-II)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>}][CF<sub>3</sub>SO<sub>3</sub>]<sub>2</sub>
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资源简介：
A 1:2:1 reaction of [n-Bu2SnO]n, trifluoromethanesulfonic acid, and 4,4′-bipyridine N,N-dioxide (BPDO-II) afforded a cocrystal (1·H2O) of the unprecedented pentahydrated diorganotin cation [{n-Bu2Sn(H2O)5}][CF3SO3]2 (1A) and its coordination product [{n-Bu2Sn(BPDO-II)2(H2O)2}][CF3SO3]2 (1B). A variation in crystallization conditions led to the isolation of a coordination polymer, [{n-Bu2Sn(μ-BPDO-II)(H2O)2}{CF3SO3}2]n (2).
创建时间：
2009-09-14
