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Free Radical-Promoted Monochloroalkylarylation of Alkenes with Chloralkanes

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https://figshare.com/articles/dataset/Free_Radical-Promoted_Monochloroalkylarylation_of_Alkenes_with_Chloralkanes/15156881
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Free radical-initiated cascade cyclization of unactivated alkenes with chloralkanes, which undergoes selective activation of the α-C­(sp3)–H bond of chloralkanes, provides a protocol for the synthesis of chlorinated heterocycles or polycyclic compounds. A series of radical inhibition experiments, radical capture operations, and radical clock tests were studied in this system.
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2021-08-12
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