Hydrogen Bond Effects: A Strategy for Improving Controllability in Organocatalytic Photoinduced Controlled Radical Polymerization Targeting High Molecular Weight
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A highly efficacious photoinduced reversible complexation-mediated polymerization (photo-RCMP) system using amino alcohol N-oxide as the catalyst has been developed, allowing access to controlled high-molecular-weight polymers of different methacrylates (Mn = 497–815 kg/mol, Đ 2 as a predominant effective regulator of radical concentration, by the studies of X-ray analysis, control experiments, density functional theory calculation, ultraviolet–vis absorption spectroscopy, etc.
创建时间:
2022-09-09



