The Silver-Promoted Phosphonation/Alkynylation of Alkene Proceeding with Radical 1,2-Alkynyl Migration
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https://figshare.com/articles/dataset/The_Silver-Promoted_Phosphonation_Alkynylation_of_Alkene_Proceeding_with_Radical_1_2-Alkynyl_Migration/9729947
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资源简介:
The
silver-promoted phosphonation/alkynylation of vinyl in α-aryl
α-alkynyl allylic alcohols with phosphine oxide was developed,
affording a series of α-alkynyl γ-ketophosphine oxides
in moderate to good yields. This procedure involved the radical 3-exo-dig cyclization, proceeding with the
radical 1,2-alkynyl migration rather than the aryl migration.
创建时间:
2019-08-19



