Synthesis and Reactivity of Novel Mesityl Boratabenzene Ligands and Their Coordination to Transition Metals
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Novel_Mesityl_Boratabenzene_Ligands_and_Their_Coordination_to_Transition_Metals/2280811
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资源简介：
The synthesis and characterization
of novel bulky mesitylboratabenzene
ligands have been achieved. The isolated boracyclohexadienes 6a,b were found to be extremely stable and could
be selectively desilylated by hydrolysis. These ligands have been
successfully coordinated to Fe(II) and Cr(II). The selective desilylation
of the boratabenzene ring was also observed in the iron complexes,
thus furnishing three ironboratabenzene sandwich complexes without
a SiMe3 group (11) and with one (10) and two (12) SiMe3 groups. Interestingly,
species 11 represents the first structurally characterized
bis(boratabenzene) metallic species not exhibiting the expected trans
geometry.
创建时间：
2016-02-17
