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Triple Boron-Cored Chromophores Bearing Discotic 5,11,17-Triazatrinaphthylene-Based Ligands

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https://figshare.com/articles/dataset/Triple_Boron_Cored_Chromophores_Bearing_Discotic_5_11_17_Triazatrinaphthylene_Based_Ligands/3102187
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资源简介:
A series of novel chromophores fused with multiple boron cores have been successfully synthesized by the complexation of three difluoroboryl or diphenylboryl at the periphery of 5,11,17-triazatrinaphthylene derivative ligands. Their sterically congested molecular scaffolds with expanded π-conjugated discotic backbones render them with unique electronic properties including large Stokes shifts, tunable electrochemical behaviors, and low-lying LUMO energy levels up to −3.18 eV.
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2016-03-14
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