Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Trifluoromethyl_Substituted_Cyclopropanes/2998540
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资源简介:
The reaction of 1-aryl-2,2,2-trifluorodiazoethanes with alkenes, catalyzed by the adamantylglycine-derived dirhodium complex Rh2(R-PTAD)4,
generates trifluoromethyl-substituted cyclopropanes with high diastereoselectivity (>94%) and enantioselectivity (88−>98%).
创建时间:
2016-02-29



