Copper-Catalyzed Regio- and Diastereoselective Additions of Boron-Stabilized Carbanions to Heteroarenium Salts: Synthesis of Azaheterocycles Containing Contiguous Stereocenters
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https://figshare.com/articles/dataset/Copper-Catalyzed_Regio-_and_Diastereoselective_Additions_of_Boron-Stabilized_Carbanions_to_Heteroarenium_Salts_Synthesis_of_Azaheterocycles_Containing_Contiguous_Stereocenters/13414835
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资源简介:
Nucleophilic addition of diborylalkyl
reagents to N-alkyl or N-acylpyridinium
and related heteroarenium
salts has been developed as a key step for the synthesis of nonaromatic
nitrogen heterocycles that contain contiguous stereogenic centers.
Derivatization of the dihydropyridine products for the synthesis of
tetrahydropyridines and piperidines have also been described.
创建时间:
2020-12-18



