Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation
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https://figshare.com/articles/dataset/Suzuki_Miyaura_Cross_Coupling_of_Unprotected_Nitrogen_Rich_Heterocycles_Substrate_Scope_and_Mechanistic_Investigation/2382994
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资源简介：
The
Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich
heterocycles using precatalysts P1 or P2 is reported. The procedure allows for the reaction of variously
substituted indazole, benzimidazole, pyrazole, indole, oxindole, and
azaindole halides under mild conditions in good to excellent yields.
Additionally, the mechanism behind the inhibitory effect of unprotected
azoles on Pd-catalyzed cross-coupling reactions is described based
on evidence gained through experimental, crystallographic, and theoretical
investigations.
创建时间：
2013-08-28
