Dinitrosyl Iron Complexes Relevant to Rieske Cluster Nitrosylation
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Dinitrosyl Iron Complexes Relevant to Rieske Cluster Nitrosylation
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2009-06-17
相关数据集
Dinitrosyl Iron Complexes (DNICs) Containing S/N/O Ligation: Transformation of Roussin's Red Ester into the Neutral {Fe(NO) 2 } 10 DNICs
Addition of the Lewis base [OPh]- to the THF solution of Roussin's red ester [Fe(μ-SC6H4-o-NHCOPh)(NO)2]2 (1) and [Fe(μ-SC6H4-o-COOH)(NO)2]2 (2), respectively, yielded the EPR-active, anionic {Fe(NO)2
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New Members of a Class of Dinitrosyliron Complexes (DNICs): Interconversion and Spectroscopic Discrimination of the Anionic {Fe(NO) 2 } 9 [(NO) 2 Fe(C 3 H 3 N 2 ) 2 ] − and [(NO) 2 Fe(C 3 H 3 N 2 )(SR)] − (C 3 H 3 N 2 = Deprotonated Imidazole; R = t Bu, Et, Ph)
The anionic {Fe(NO)2}9 DNIC [(NO)2Fe(C3H3N2)2]− (2) (C3H3N2 = deprotonated imidazole) containing the deprotonated imidazole-coordinated ligands and DNICs [(NO)2Fe(C3H3N2)(SR)]− (R = tBu (3), Et (4), P
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Relative Binding Affinity of Thiolate, Imidazolate, Phenoxide, and Nitrite Toward the {Fe(NO) 2 } Motif of Dinitrosyl Iron Complexes (DNICs): The Characteristic Pre-Edge Energy of {Fe(NO) 2 } 9 DNICs
The synthesis, characterization, and transformation of the anionic {Fe(NO)2}9 dinitrosyl iron complexes (DNICs) [(NO)2Fe(ONO)2]− (1), [(NO)2Fe(OPh)2]− (2), [(NO)2Fe(OPh)(C3H3N2)]− (3) (C3H3N2 = imidaz
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A Series of Iron Nitrosyl Complexes {Fe–NO} 6–9 and a Fleeting {Fe–NO} 10 Intermediate en Route to a Metalacyclic Iron Nitrosoalkane
Iron–nitrosyls have fascinated chemists for a long time due to the noninnocent nature of the NO ligand that can exist in up to five different oxidation and spin states. Coordination to an open-shell i
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Bismercaptoethanediazacyclooctane as a N 2 S 2 Chelating Agent and Cys−X−Cys Mimic for Fe(NO) and Fe(NO) 2
The N-protonated bismercaptoethanediazacyclooctane serves as a bidentate dithiolate ligand to oxidized Fe(NO)2 of Enemark−Feltam notation, E−F {Fe(NO)2}, mimicking Cys−X−Cys binding of Fe(NO)2 to prot
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