Cooperative Hydrogen-Bonding Effects in Silanediol Catalysis
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https://figshare.com/articles/dataset/Cooperative_Hydrogen_Bonding_Effects_in_Silanediol_Catalysis/2565553
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The importance of cooperative hydrogen-bonding effects and SiOH-acidification is described for silanediol catalysis. NMR binding, X-ray, and computational studies provide support for a unique dimer resulting from silanediol self-recognition. The significance of this cooperative hydrogen-bonding is demonstrated using novel fluorinated silanediol catalysts for the addition of indoles and N,N-dimethyl-m-anisidine to trans-β-nitrostyrene.
创建时间：
2016-02-22
