Structure, Conformation, Stereodynamics, and Absolute Configuration of the Atropisomers of Fluorenylidene Derivatives
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https://figshare.com/articles/dataset/Structure_Conformation_Stereodynamics_and_Absolute_Configuration_of_the_Atropisomers_of_Fluorenylidene_Derivatives/2686597
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资源简介:
The barrier for the interconversion of the conformational atropisomers of an aryl fluorenylidene derivative was determined by variable-temperature NMR technique. In the case of a more hindered compound the two atropisomers were isolated and the structure determined by X-ray diffraction. The absolute configuration was assigned by theoretical interpretation of the Electronic Circular Dichroism spectrum (ECD).
创建时间:
2011-03-04



