Palladium-Catalyzed Formal Hydroacylation of Allenes Employing Acid Chlorides and Hydrosilanes
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The palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes has been achieved. The reactions proceed with commercially available Pd(OAc)2 as a catalyst and HSi(iPr)3 as a reducing reagent, giving the corresponding α,β-unsaturated ketones regio- and stereoselectively.
创建时间：
2016-02-19
