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Glycoluril Dimer Isomerization under Aqueous Acidic Conditions Related to Cucurbituril Formation

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https://figshare.com/articles/dataset/Glycoluril_Dimer_Isomerization_under_Aqueous_Acidic_Conditions_Related_to_Cucurbituril_Formation/2462275
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资源简介:
A water-soluble methylene-bridged glycoluril dimer 2S was isolated. It was shown that 2S is the only kinetic product of the reaction between glycoluril derivative 1 and paraformaldehyde. Compound 2S is subsequently intermolecularly transformed into its diastereomer 2C. The kinetics and thermodynamics of the S- to C-shaped dimer isomerization were investigated under reaction conditions similar to those for cucurbituril synthesis.
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2016-02-20
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