Novel Reaction Pathways for 2-Pyridone [4+4] Photoadducts
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Novel_Reaction_Pathways_for_2_Pyridone_4_4_Photoadducts/3070021
下载链接
链接失效反馈官方服务：
资源简介：
Transannular ring closure of a pyridone−furan [4+4] photoadduct has been evaluated in a model system. A combination of nitrogen substitution
and an isopropyl group gave full control of the four new stereogenic centers. Chlorination transformed the 1,5-cyclooctadiene to a [4.2.0] ring
system instead of to the expected [3.3.0] ring system. Changing an alkene to an enone suppressed this pathway and led to a new rearrangement,
converting the 5-8-5 ring system to a 6-7-5 system.
创建时间：
2016-03-01
