A Tripodal Ligand Constructed from Mesoionic Carbene Donors
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https://figshare.com/articles/dataset/A_Tripodal_Ligand_Constructed_from_Mesoionic_Carbene_Donors/2360731
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资源简介:
A tripodal ligand constructed solely
from mesoionic carbene donors
is reported. The donor strength of this ligand is lower than most
imidazol-2-ylidene-based tris(carbene)borate ligands, as measured
by IR spectroscopy of {NiNO}10 and {Mn(CO)3}+ derivatives. The attenuated donor strength is proposed to
be due to the collective electron-withdrawing effect of the ligand’s
aryl substituents.
创建时间:
2016-02-18



