A Tripodal Ligand Constructed from Mesoionic Carbene Donors
收藏NIAID Data Ecosystem2026-03-08 收录
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A tripodal ligand constructed solely from mesoionic carbene donors is reported. The donor strength of this ligand is lower than most imidazol-2-ylidene-based tris(carbene)borate ligands, as measured by IR spectroscopy of {NiNO}10 and {Mn(CO)3}+ derivatives. The attenuated donor strength is proposed to be due to the collective electron-withdrawing effect of the ligand’s aryl substituents.
创建时间:
2016-02-18



