遇见数据集

A Tripodal Ligand Constructed from Mesoionic Carbene Donors

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NIAID Data Ecosystem2026-03-08 收录
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A tripodal ligand constructed solely from mesoionic carbene donors is reported. The donor strength of this ligand is lower than most imidazol-2-ylidene-based tris­(carbene)­borate ligands, as measured by IR spectroscopy of {NiNO}10 and {Mn­(CO)3}+ derivatives. The attenuated donor strength is proposed to be due to the collective electron-withdrawing effect of the ligand’s aryl substituents.

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2016-02-18
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