Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts

Original data for the publication https://doi.org/10.1002/chem.202101548 <strong>Table of Contents</strong> 1. Synthesis 1.1. Compounds <strong>(<em>R*</em>,<em>R*,S</em>)-25 </strong>and<strong> (<em>S*</em>,<em>S*,S</em>)-25</strong> 1.1.1. NMR 1.1.2. Procedure 1.2. Compounds <strong>(<em>R*</em>,<em>R*</em>)-5 </strong>and <strong>(<em>S*</em>,<em>S*</em>)-5</strong> 1.2.1. Chiral GC Data 1.2.2. Procedure 1.3. Compound <strong>34</strong> 1.3.1. NMR 1.3.2. Procedure 1.4. Compound <strong>35</strong> 1.4.1. NMR 1.4.2. Procedure 1.5. Compound <strong>(<em>R*</em>)-3</strong> 1.5.1. Procedure 1.6. Compound <strong>(<em>S*</em>)-6</strong> 1.6.1. Chiral GC Data 1.6.2. Procedure 2. Kinetic Studies 2.1. Table S1 2.1.1. NMR Spectra for Table S1 2.1.2. Procedures with Anion-pi Catalyst <strong>10</strong> 2.1.3 Procedures with Capsule <strong>15</strong> 2.2. Table S2 2.2.1. NMR Spectra for Table S2 2.2.2. Procedures with Anion-pi Catalyst <strong>10</strong> 2.2.3 Procedures with Capsule <strong>15</strong> 2.3. Table S3 2.3.1. NMR Spectra for Table S3 2.3.2. Procedures with Anion-pi Catalyst <strong>10</strong> 2.3.3 Procedures with Capsule <strong>15</strong> 3. Catalysis 3.1. Co-Catalyst Screening 3.1.1. NMR Spectra for Scheme S3 3.1.2. Procedures with Anion-pi Catalyst <strong>11</strong> 3.2 Catalyst Comparison on the Mono-Epoxide Level 3.2.1. NMR Spectra for Scheme S4 3.2.2. Procedures with Different Catalysts 3.3. Catalyst Comparison on the Di-Epoxide Level 3.3.1. NMR Spectra for Scheme S5 3.3.2. Procedures with Different Catalysts 3.4. Asymmetric Autocatalysis Assay 3.4.1. Chiral GC Data for Schemes S20 and S21 3.4.2. Procedures with Different Substrates