Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products
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Mononitrosyldiiron complexes having either an [FeII·{FeNO}7] or an [FeIII·{FeNO}7] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [FeIII·{FeNO}7] are described.
创建时间：
2016-02-18
