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Catalytic Dehydrogenation of (Di)Amine-Boranes with a Geometrically Constrained Phosphine-Borane Lewis Pair
The o-phenylene bridged phosphine-borane iPr2P(o-C6H4)B(Fxyl)2 2 was prepared. Despite ring strain, it adopts a closed form, as substantiated by NMR, XRD, and DFT analyses. However, the correspondi
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Taking Solution Proton NMR to Its Extreme: Prediction and Detection of a Hydride Resonance in an Intermediate-Spin Iron Complex
Guided by DFT based modeling the chemical shift range of a hydride resonance in the proton nuclear magnetic resonance (NMR) spectrum of the intermediate-spin, square planar iron complex tBu(PNP)Fe–H
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Metal-Free Aromatic Hydrogenation: Aniline to Cyclohexyl-amine Derivatives
Hydrogenation of the N-bound phenyl rings of amines, imines, and aziridine is achieved in the presence of H2 and B(C6F5)3, affording the corresponding N-cyclohexylammonium hydridoborate salts.
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Broadening the Scope of Group 4 Hydroamination Catalysis Using a Tethered Ureate Ligand
Broadening the Scope of Group 4 Hydroamination Catalysis Using a Tethered Ureate Ligand
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DataSheet1_Boosting the Productivity of H2-Driven Biocatalysis in a Commercial Hydrogenation Flow Reactor Using H2 From Water Electrolysis.docx
Translation of redox biocatalysis into a commercial hydrogenation flow reactor, with in-built electrolytic H2 generation, was achieved using immobilized enzyme systems. Carbon-supported biocatalysts w
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