Synthesis of Neplanocin A and Its 3′-Epimer via an Intramolecular Baylis–Hillman Reaction
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Neplanocin_A_and_Its_3_Epimer_via_an_Intramolecular_Baylis_Hillman_Reaction/2257357
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The key cyclopentenyl intermediate 11b was synthesized in 4 steps from d-ribose in 41% overall yield via an efficient intramolecular Baylis–Hillman reaction. This novel key intermediate can be modified easily and transformed to neplanocin A (1a) and its 3′-epimer (1b).
创建时间：
2016-02-16
