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Reactivity of [Ru<sub>3</sub>(CO)<sub>12</sub>] with Dibenzothiophene, Methylbenzothiophene, and Methyldibenzothiophene

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NIAID Data Ecosystem2026-03-06 收录
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The reaction of dibenzothiophene (DBT) with [Ru3(CO)12] in heptane affords the dinuclear complex [Ru2(C12H8)(μ-CO)(CO)5], derived from a double C−S bond activation−desulfurization process. The reaction of this complex with H2 under very mild conditions leads to the release of biphenyl.

创建时间:
2016-08-26
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