Synthesis of the ABC Tricyclic System of Daphnicyclidin A
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https://figshare.com/articles/dataset/Synthesis_of_the_ABC_Tricyclic_System_of_Daphnicyclidin_A/4754404
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A substrate-stereocontrolled synthesis of the ABC tricyclic system of daphnicyclidin A is developed. The key reactions include an efficient tandem N-allylation–SN2′ reaction to assemble 2,3,4-cis trisubstituent pyrrolidine ring C and two intramolecular Horner–Wadsworth–Emmons reactions to construct cycloheptanone ring A and piperidine ring B.
创建时间：
2017-03-15
