Ruthenium-Catalyzed Cyclization of Aromatic Nitriles with Alkenes: Stereoselective Synthesis of (Z)‑3-Methyleneisoindolin-1-ones
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Ruthenium_Catalyzed_Cyclization_of_Aromatic_Nitriles_with_Alkenes_Stereoselective_Synthesis_of_i_Z_i_3_Methyleneisoindolin_1_ones/2253760
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资源简介：
Aromatic nitriles underwent cyclization with activated alkenes in the presence of a ruthenium catalyst, AgSbF6, and Cu(OAc)2·H2O providing substituted 3-methyleneisoindolin-1-ones with high Z-stereoselectivity. The Z-stereoselectivity of the 3-methyleneisoindolin-1-one moiety was controlled by the intramolecular hydrogen bonding.
创建时间：
2016-02-16
