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A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules

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Figshare2016-11-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Cyanide-Bridged_Magnetically_Switchable_Cage_with_Encapsulated_Water_Molecules/4238675
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A cage complex, H2O@[Co5Fe4], was found to encapsulate two water molecules during its self-assembly. The complex exhibited remarkable multifunctionality, combining magnetic switching from the thermal electron-transfer-coupled spin transition of the cage host and dipolar reorientational motion of the confined water, as evidenced by permittivity measurements, density functional theory calculations, and solid-state 2H NMR spectra.
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2016-11-17
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