Total Synthesis of (−)-Luminacin D
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https://figshare.com/articles/dataset/Total_Synthesis_of_Luminacin_D/3181408
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资源简介：
A second-generation synthesis of
(−)-luminacin D based on
an early stage introduction of the trisubstituted epoxide group is
reported, allowing access to the natural product in an improved yield
and a reduced number of steps (5.4%, 17 steps vs 2.6%, 19 steps).
A full account of the optimization work is provided, with the reversal
of stereoselection in the formation of the C4 alcohol in equally excellent
diastereoselectivity as the key improvement.
创建时间：
2016-05-02
