Total Synthesis of (−)-Luminacin D
收藏NIAID Data Ecosystem2026-03-09 收录
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资源简介：
A second-generation synthesis of (−)-luminacin D based on an early stage introduction of the trisubstituted epoxide group is reported, allowing access to the natural product in an improved yield and a reduced number of steps (5.4%, 17 steps vs 2.6%, 19 steps). A full account of the optimization work is provided, with the reversal of stereoselection in the formation of the C4 alcohol in equally excellent diastereoselectivity as the key improvement.
创建时间：
2016-05-02
