Template Synthesis of Decaphyrin without Meso-Bridges: Cyclo[10]pyrrole
收藏Figshare2016-06-17 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Template_Synthesis_of_Decaphyrin_without_i_Meso_i_-Bridges_Cyclo_10_pyrrole/3423581
下载链接
链接失效反馈官方服务：
资源简介：
An acenaphthylene-fused cyclo[10]pyrrole 1b was selectively synthesized via an oxidative coupling reaction of the corresponding 2,2′-bipyrrole with the appropriate dianion template, croconate anion. The structure of 1b as the isolated largest cyclo[n]pyrrole was elucidated by X-ray crystallographic analysis. The absorption spectrum exhibited a markedly red-shifted, intensified L band at 1982 nm, which was interpreted by application of Michl’s perimeter and Gouterman’s 4-orbital models, supported by magnetic circular dichroism (MCD) data and theoretical calculations.
创建时间：
2016-06-17
