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Efficient Catalysis of Ammonia Borane Dehydrogenation

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NIAID Data Ecosystem2026-03-06 收录
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In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and [NH2BH2]5. A metal borohydride complex has been isolated as a dormant form of the catalyst which can be reactivated by reaction with H2.

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2006-09-20
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