Studies on the Synthesis of Gymnodimine. Construction of the Spiroimine Portion via Diels−Alder Cycloaddition
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An azaspiro[5.5]undecadiene corresponding to a subunit of the shellfish toxin gymnodimine was synthesized by Diels−Alder cycloaddition. One member of the pair of stereoisomeric adducts was transformed to a spiroimine, which will serve as the core around which the macrocyclic portion of the toxin will be assembled.
创建时间：
2003-12-25
