Total Syntheses of (±)-Omphadiol and (±)-Pyxidatol C through a Cis-Fused 5,7-Carbocyclic Common Intermediate
收藏Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Total_Syntheses_of_Omphadiol_and_Pyxidatol_C_through_a_i_Cis_i_Fused_5_7_Carbocyclic_Common_Intermediate/2285332
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Total syntheses of omphadiol and pyxidatol C, two isomeric africanane sesquiterpenes sharing identical 5-7-3 tricyclic carbon skeletons yet containing distinct oxidation patterns, are reported. The trans-fused 5,7-carbocycles in the terpenoids characterized by specific oxidation patterns were derived from a readily available cis-fused 5,7-carbocyclic common intermediate.
创建时间：
2016-02-17
