Total Syntheses of (±)-Omphadiol and (±)-Pyxidatol C through a Cis-Fused 5,7-Carbocyclic Common Intermediate
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Total syntheses of omphadiol and pyxidatol C, two isomeric africanane sesquiterpenes sharing identical 5-7-3 tricyclic carbon skeletons yet containing distinct oxidation patterns, are reported. The trans-fused 5,7-carbocycles in the terpenoids characterized by specific oxidation patterns were derived from a readily available cis-fused 5,7-carbocyclic common intermediate.
创建时间：
2016-02-17
