Ferroelectric Heterobimetallic Clusters with Ferromagnetic Interactions
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Two homochiral trinuclear clusters, {(MeTp)2Fe2(CN)6Ni[(1R,2R)-chxn]2} (1) and {(MeTp)2Fe2(CN)6Ni[(1S,2S)-chxn]2} (2) [chxn = 1,2-diaminocyclohexane; MeTp = methyltris(pyrazolyl)borate], have been synthesized and structurally characterized. Ferroelectric and magnetic measurements reveal that they are rare examples of metal−organic compounds bearing ferroelectricity and intramolecular ferromagnetic interactions.
创建时间:
2008-09-15



