A More Reactive Trigonal-Bipyramidal High-Spin Oxoiron(IV) Complex with a cis-Labile Site
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_More_Reactive_Trigonal_Bipyramidal_High_Spin_Oxoiron_IV_Complex_with_a_cis_Labile_Site/2624358
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The trigonal-bipyramidal high-spin (S = 2) oxoiron(IV) complex [FeIV(O)(TMG2dien)(CH3CN)]2+ (7) was synthesized and spectroscopically characterized. Substitution of the CH3CN ligand by anions, demonstrated here for X = N3– and Cl–, yielded additional S = 2 oxoiron(IV) complexes of general formulation [FeIV(O)(TMG2dien)(X)]+ (7-X). The reduced steric bulk of 7 relative to the published S = 2 complex [FeIV(O)(TMG3tren)]2+ (2) was reflected by enhanced rates of intermolecular substrate oxidation.
创建时间：
2016-02-23
