SuFEx in Metal–Organic Frameworks: Versatile Postsynthetic Modification Tool
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https://figshare.com/articles/dataset/SuFEx_in_Metal_Organic_Frameworks_Versatile_Postsynthetic_Modification_Tool/7122863
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资源简介：
A new
type of click reaction, sulfur(VI) fluoride exchange (SuFEx), has
been utilized to prepare five postsynthetically modified UiO-67 series metal–organic frameworks (MOFs). The postsynthetic
modification (PSM) via SuFEx can be achieved selectively for the sulfonyl
fluoride (R-SO2F) without degrading the MOF structure as
confirmed by X-ray crystallographic analysis. The present SuFEx method
provides a straightforward tool for introducing new functionality
inside MOFs. Introduction of an imidazolium group into the MOF afforded
a heterogeneous catalyst for the benzoin condensation reaction.
创建时间：
2018-09-25
