Diastereoselective and Enantioselective Desymmetrization of α‑Substituted Cyclohexadienones via Intramolecular Stetter Reaction
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Highly diastereoselective and enantioselective desymmetrization of α-substituted cyclohexadienones via NHC-catalyzed intramolecular Stetter reaction was realized. Amino-indanol derived triazolium salt bearing a C6F5 group was found to be the optimal catalyst precursor in the intramolecular Stetter reaction furnishing tricyclic products bearing multi-stereocenters in up to 96% yield and >99% ee.
创建时间：
2016-02-20
