XMCD study of UCu2P2 at high pressure

B2FIND2026-04-30 收录

高压磁学

铀配合物化学

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The Zintl phase UCu2P2 has record high ferromagnetic ordering temperature TC = 216 K among U-based compounds, which further increases with increasing pressure. Electrical...

Reduced Uranium Complexes: Synthetic and DFT Study of the Role of π Ligation in the Stabilization of Uranium Species in a Formal Low-Valent State

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Reaction of UCl4(THF)4 with 1,3-[2,5-(i-Pr)2PhNC(CH2)]2C6H4Li2 produced a complex formulated as [{1,3-[2,5-(i-Pr)2PhNC(CH2)]2C6H4}UCl3][Li(THF)4] (1) that exhibits a nonagostic interaction between o

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Redox behavior of [UO2(gha)DMSO]−/UO2(gha)DMSO couple (gha = glyoxal bis(2-hydroxanil)ate, DMSO = dimethyl sulfoxide) in DMSO solution was investigated by cyclic voltammetry and UV–vis–NIR spectro

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Magnetic Exchange Coupling in Chloride-Bridged 5f−3d Heterometallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate Dimer

分子磁交换耦合

铀配合物化学

The homoleptic dimer complex [U(Me2Pz)4]2 (Me2Pz− = 3,5-dimethylpyrazolate) was obtained upon reacting UCl4 with KMe2Pz in THF, followed by extraction into toluene. The structure of the dimer consists

NIAID Data Ecosystem20

Photochemical Water Oxidation and Origin of Nonaqueous Uranyl Peroxide Complexes

铀配合物化学

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Sunlight photolysis of uranyl nitrate and uranyl acetate solutions in pyridine produces uranyl peroxide complexes. To answer longstanding questions about the origin of these complexes, we conducted a

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Probing the Reactivity and Electronic Structure of a Uranium(V) Terminal Oxo Complex

铀配合物化学

计算化学DFT

Treatment of the U(III)–ylide adduct U(CH2PPh3)(NR2)3 (1, R = SiMe3) with TEMPO generates the U(V) oxo metallacycle [Ph3PCH3][U(O)(CH2SiMe2NSiMe3)(NR2)2] (2) via O-atom transfer, in good yield. Oxidat

Figshare2016-02-23 更新30

XMCD study of UCu2P2 at high pressure

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