Total Synthesis of ent-Plagiochianin B
收藏Figshare2021-01-30 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_i_ent_i_-Plagiochianin_B/13668886
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An enantioselective total synthesis of plagiochianin B is described that employs (+)-3-carene as its point of departure and delivers the enantiomer of the natural product. Key features of the synthesis include a palladium-mediated regioselective oxidative cleavage of an olefin residing on a pyridine derived from a 6π-azatriene electrocyclization.
创建时间：
2021-01-30
