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Iminium Ion Cascade Reaction in the Total Synthesis of (+)-Vincadifformine

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Iminium_Ion_Cascade_Reaction_in_the_Total_Synthesis_of_Vincadifformine/2618542
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An iminium ion triggered cascade reaction is described in the total synthesis of (+)-vincadifformine by the coupling of 3,3-substituted tetrahydropyridine and indole derivative. The strategy allows simultaneous construction of two new rings, three new sigma bonds, and two new stereogenic centers in one pot with complete stereochemical control.
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2016-02-23
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