Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes
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https://figshare.com/articles/dataset/Asymmetric_Palladium_Catalyzed_Directed_Intermolecular_Fluoroarylation_of_Styrenes/2030151
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资源简介：
A mild
catalytic asymmetric direct fluoro-arylation of styrenes
has been developed. The palladium-catalyzed three-component coupling
of Selectfluor, a styrene and a boronic acid, provides chiral monofluorinated
compounds in good yield and in high enantiomeric excess. A mechanism
proceeding through a Pd(IV)-fluoride intermediate is proposed for
the transformation and synthesis of an sp3 C–F bond.
创建时间：
2015-12-17
