Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis by Chloride Abstraction from N‑Heterocyclic Carbene-Stabilized Chlorometallogermylenes
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Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)2C6H3) gave a cationic metallogermylene or dicationic dimetallodigermenes.
创建时间:
2016-02-16



