Catalytic Enantioselective Oxaziridination
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Oxaziridination/2610469
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资源简介:
The first catalytic enantioselective synthesis of oxaziridines is presented. The oxidation of aryl and alkyl aldimines with m-CPBA under organocatalytic conditions using cinchona alkaloid-derived catalysts furnished optically active oxaziridines in good yields and high enantioselectivities (up to 94% ee). Mechanistic investigations indicate a stepwise enantioselective oxidation process.
创建时间:
2016-02-22



