Synthesis, Resolution, and Absolute Configuration of Chiral 4,4′-Bipyridines
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A chiral polyhalogenated 4,4′-bipyridine derivative is described allowing an easy access to a new family of chiral 4,4′-bipyridines by site-selective cross-coupling reactions. The absolute configurations of all the HPLC separated enantiomers were determined by X-ray diffraction and electronic circular dichroism coupled with time-dependent density functional theory calculations.
创建时间：
2016-02-21
