Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged Mn<sub>3</sub><sup>III</sup>Mn<sub>2</sub><sup>II</sup> Single-Molecule Magnets
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We prepared three structurally related Mn3IIIMn2II complexes that possess S ≈ 1−11 spin ground states as a result of variations in the geometry and identity of μ2-η1:η1 bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (Ueff).
创建时间：
2016-02-25
